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Phosphorus-doped Ni–Co sulfides connected by carbon nanotubes for flexible hybrid supercapacitor

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 491-503 doi: 10.1007/s11705-022-2257-9

摘要： As promising electrode materials for supercapacitors, nickel-cobalt bimetallic sulfides render the advantages of abundant redox reactions and inherently high conductivity. However, in general, unsatisfactory performance of low specific capacity, low rate capability, and fast capacity loss exist in Ni–Co sulfide electrodes. Herein, we rationally regulate phosphorus-doped nickel–cobalt sulfides (P-NCS) to enhance the electrochemical performance by gas–solid phosphorization. Moreover, carbon nanotubes (CNTs) as conductive additives are added to improve the cycle stability and conductivity and form the composite P-NCS/C/CNT. According to density functional theory, more electrons near the Fermi surface of P-NCS are demonstrated notionally than those of simple CoNi2S4. Electrochemical results manifest that P-NCS/C/CNT exhibits superior electrochemical performance, e.g., high specific capacity (932.0 C∙g‒1 at 1 A∙g‒1), remarkable rate capability (capacity retention ratio of 69.1% at 20 A∙g‒1), and lower charge transfer resistance. More importantly, the flexible hybrid asymmetric supercapacitor is assembled using P-NCS/C/CNT and activated carbon, which renders an energy density of 34.875 W·h∙kg‒1 at a power density of 375 W∙kg‒1. These results show that as-prepared P-NCS/C/CNT demonstrates incredible possibility as a battery-type electrode for high-performance supercapacitors.

关键词： cobalt nickel sulfide     phosphorus-doping     hybrid supercapacitor     carbon nanotube     density functional theory    

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CC@BCN@PANI core-shell nanoarrays as ultra-high cycle stability cathode for Zn-ion hybrid supercapacitors

《能源前沿（英文）》 2023年 第17卷 第4期   页码 555-566 doi: 10.1007/s11708-023-0882-8

摘要： Exploring cathode materials that combine excellent cycling stability and high energy density poses a challenge to aqueous Zn-ion hybrid supercapacitors (ZHSCs). Herein, polyaniline (PANI) coated boron-carbon-nitrogen (BCN) nanoarray on carbon cloth surface is prepared as advanced cathode materials via simple high-temperature calcination and electrochemical deposition methods. Because of the excellent specific capacity and conductivity of PANI, the CC@BCN@PANI core-shell nanoarrays cathode shows an excellent ion storage capability. Moreover, the 3D nanoarray structure can provide enough space for the volume expansion and contraction of PANI in the charging/discharging cycles, which effectively avoids the collapse of the microstructure and greatly improves the electrochemical stability of PANI. Therefore, the CC@BCN@PANI-based ZHSCs exhibit superior electrochemical performances showing a specific capacity of 145.8 mAh/g, a high energy density of 116.78 Wh/kg, an excellent power density of 12 kW/kg, and a capacity retention rate of 86.2% after 8000 charge/discharge cycles at a current density of 2 A/g. In addition, the flexible ZHSCs (FZHSCs) also show a capacity retention rate of 87.7% at the current density of 2 A/g after 450 cycles.

关键词： CC@BCN@PANI cathode     Zn-ion hybrid supercapacitor     core-shell nanoarrays     high energy density     ultra-high cycle stability    

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the grain boundary: a promising strategy to configure NiCoPO/NiCoP nanowire arrays for ultra-stable supercapacitor

《化学科学与工程前沿（英文）》 2022年 第16卷 第8期   页码 1259-1267 doi: 10.1007/s11705-021-2132-0

摘要： NiCoP4O12/NiCoP nanorod-like arrays with tunable grain boundary density and pores were synthesized by the processes composed of hydrothermal and pyrolysis, in which, the electron structure of Ni and Co atoms characterized by X-ray photoelectron spectroscopy was contemporaneous inverse manipulated. The optimized NiCoP4O12/NiCoP arrays have a high specific capacitance of 507.8 μAh∙cm–2 at 1 mA∙cm–2, and good rate ability of 64.7% retention at 30-folds increased current density. Importantly, an ultra-stable ability, 88.5% of retention after 10000 cycles, was achieved in an asymmetric cell assembled of the NiCoP4O12/NiCoP arrays with activated carbon. In addition, the energy and power densities of an asymmetric cell were higher than those of other work, demonstrating as-prepared NiCoP4O12/NiCoP arrays are promising electrodes for supercapacitors.

关键词： NiCo     array electrode     grain boundary     stability     supercapacitor    

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Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2088-2100 doi: 10.1007/s11705-023-2352-6

摘要： Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor application

关键词： nickel ferrite conductivity     carbon oxygen vacancies    

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Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications

《化学科学与工程前沿（英文）》 2022年 第16卷 第4期   页码 475-483 doi: 10.1007/s11705-021-2070-x

摘要： Surface functionalization or modification to introduce more oxygen-containing functional groups to biochar is an effective strategy for tuning the physicochemical properties and promoting follow-up applications. In this study, non-thermal plasma was applied for biochar surface carving before being used in contaminant removal and energy storage applications. The results showed that even a low dose of plasma exposure could introduce a high number density of oxygen-functional groups and enhance the hydrophilicity and metal affinity of the pristine biochar. The plasma-treated biochar enabled a faster metal-adsorption rate and a 40% higher maximum adsorption capacity of heavy metal ion Pb2+. Moreover, to add more functionality to biochar surface, biochar with and without plasma pre-treatment was activated by KOH at a temperature of 800 °C. Using the same amount of KOH, the plasma treatment resulted in an activated carbon product with the larger BET surface area and pore volume. The performance of the treated activated carbon as a supercapacitor electrode was also substantially improved by>30%. This study may provide guidelines for enhancing the surface functionality and application performances of biochar using non-thermal-based techniques.

关键词： non-thermal plasma     surface functionalization     biochar modification     wastewater treatment     supercapacitor    

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Intelligent hybrid power generation system using new hybrid fuzzy-neural for photovoltaic system and

Alireza REZVANI,Ali ESMAEILY,Hasan ETAATI,Mohammad MOHAMMADINODOUSHAN

《能源前沿（英文）》 2019年 第13卷 第1期   页码 131-148 doi: 10.1007/s11708-017-0446-x

摘要： Photovoltaic (PV) generation is growing increasingly fast as a renewable energy source. Nevertheless, the drawback of the PV system is intermittent because of depending on weather conditions. Therefore, the wind power can be considered to assist for a stable and reliable output from the PV generation system for loads and improve the dynamic performance of the whole generation system in the grid connected mode. In this paper, a novel topology of an intelligent hybrid generation system with PV and wind turbine is presented. In order to capture the maximum power, a hybrid fuzzy-neural maximum power point tracking (MPPT) method is applied in the PV system. The average tracking efficiency of the hybrid fuzzy-neural is incremented by approximately two percentage points in comparison with the conventional methods. The pitch angle of the wind turbine is controlled by radial basis function network-sliding mode (RBFNSM). Different conditions are represented in simulation results that compare the real power values with those of the presented methods. The obtained results verify the effectiveness and superiority of the proposed method which has the advantages of robustness, fast response and good performance. Detailed mathematical model and a control approach of a three-phase grid-connected intelligent hybrid system have been proposed using Matlab/Simulink.

关键词： photovoltaic     wind turbine     hybrid system     fuzzy logic controller     genetic algorithm     RBFNSM    

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Robust ensemble of metamodels based on the hybrid error measure

《机械工程前沿（英文）》 2021年 第16卷 第3期   页码 623-634 doi: 10.1007/s11465-021-0641-7

摘要： Metamodels have been widely used as an alternative for expensive physical experiments or complex, time-consuming computational simulations to provide a fast but accurate analysis. However, challenge remains in the prior determination of the most suitable metamodel for a particular case because of the lack of information about the actual behavior of a system. In addition, existing studies on metamodels have largely restricted on solving deterministic problems (e.g., data from finite element models), whereas some real-life engineering problems (e.g., data from physical experiment) are stochastic problems with noisy data. In this work, a robust ensemble of metamodels (EMs) is proposed by combining three regression stand-alone metamodels in a weighted sum form. The weight factor is adaptively determined according to the hybrid error metric, which combines global and local error measures to improve the accuracy of the EMs. Furthermore, three typical individual metamodels that can filter noise are selected to construct the EMs to extend their application in practical engineering problems. Three well-known benchmark problems with different levels of noise and three engineering problems are used to verify the effectiveness of the proposed EMs. Results show that the proposed EMs have higher accuracy and robustness than the individual metamodels and other typical EMs in major cases.

关键词： metamodel     ensemble of metamodels     hybrid error measure     stochastic problem    

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Design method and verification of a hybrid prosthetic mechanism with energy-damper clutchable device

《机械工程前沿（英文）》 2021年 第16卷 第4期   页码 747-764 doi: 10.1007/s11465-021-0644-4

摘要： Transfemoral amputees (TAs) have difficulty in mobility during walking, such as restricted movement of lower extremity and body instability, yet few transfemoral prostheses have explored human-like multiple motion characteristics by simple structures to fit the kinesiology, biomechanics, and stability of human lower extremity. In this work, the configurations of transfemoral prosthetic mechanism are synthesized in terms of human lower-extremity kinesiology. A hybrid transfemoral prosthetic (HTP) mechanism with multigait functions is proposed to recover the gait functions of TAs. The kinematic and mechanical performances of the designed parallel mechanism are analyzed to verify their feasibility in transfemoral prosthetic mechanism. Inspired by motion–energy coupling relationship of the knee, a wearable energy-damper clutched device that can provide energy in knee stance flexion to facilitate the leg off from the ground and can impede the leg’s swing velocity for the next stance phase is proposed. Its co-operation with the springs in the prismatic pairs enables the prosthetic mechanism to have the energy recycling ability under the gait rhythm of the knee joint. Results demonstrate that the designed HTP mechanism can replace the motion functions of the knee and ankle to realize its multimode gait and effectively decrease the peak power of actuators from 94.74 to 137.05 W while maintaining a good mechanical adaptive stability.

关键词： hybrid transfemoral prosthetic mechanism     energy recycling     wearable mechanical clutched device     mechanical adaptive stability    

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Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1065-1074 doi: 10.1007/s11705-023-2313-0

摘要： Lignocellulosic biomass such as plants and agricultural waste are ideal to tackle the current energy crisis and energy-related environmental issues. Carbon-rich lignin is abundant in lignocellulosic biomass, whose high-value transformation and utilization has been the most urgent problem to be solved. Herein, we propose a method for the preparation of porous carbon from lignin employing an H3PO4-assisted hydrothermal method. We characterize the as-prepared lignin-derived porous carbon and investigate its potential for energy storage. After assisted hydrothermal treatment followed by carbonization at 800 °C, the lignin-derived porous carbon displays a high specific capacitance (223.6 F·g–1 at 0.1 A·g–1) and excellent cycling ability with good capacitance retention. In this present study, the resultant lignin-derived porous carbon was used as the electrode of a supercapacitor, illustrating yet another potential high-value use for lignin, namely as a candidate for the sustainable fabrication of main supercapacitor components.

关键词： lignin     porous carbon     electrode     supercapacitor    

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Diffusion process in enzyme–metal hybrid catalysts

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 921-929 doi: 10.1007/s11705-022-2144-4

摘要： Enzyme–metal hybrid catalysts bridge the gap between enzymatic and heterogeneous catalysis, which is significant for expanding biocatalysis to a broader scope. Previous studies have demonstrated that the enzyme–metal hybrid catalysts exhibited considerably higher catalytic efficiency in cascade reactions, compared with that of the combination of separated enzyme and metal catalysts. However, the precise mechanism of this phenomenon remains unclear. Here, we investigated the diffusion process in enzyme–metal hybrid catalysts using Pd/lipase-Pluronic conjugates and the combination of immobilized lipase (Novozyme 435) and Pd/C as models. With reference to experimental data in previous studies, the Weisz–Prater parameter and efficiency factor of internal diffusion were calculated to evaluate the internal diffusion limitations in these catalysts. Thereafter, a kinetic model was developed and fitted to describe the proximity effect in hybrid catalysts. Results indicated that the enhanced catalytic efficiency of hybrid catalysts may arise from the decreased internal diffusion limitation, size effect of Pd clusters and proximity of the enzyme and metal active sites, which provides a theoretical foundation for the rational design of enzyme–metal hybrid catalysts.

关键词： enzyme–metal hybrid catalyst     internal diffusion     proximity effect     kinetic model    

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Powertrain control of a solar photovoltaic-battery powered hybrid electric vehicle

P. PADMAGIRISAN, V. SANKARANARAYANAN

《能源前沿（英文）》 2019年 第13卷 第2期   页码 296-306 doi: 10.1007/s11708-018-0605-8

摘要： This paper proposes a powertrain controller for a solar photovoltaic battery powered hybrid electric vehicle (HEV). The main objective of the proposed controller is to ensure better battery management, load regulation, and maximum power extraction whenever possible from the photovoltaic panels. The powertrain controller consists of two levels of controllers named lower level controllers and a high-level control algorithm. The lower level controllers are designed to perform individual tasks such as maximum power point tracking, battery charging, and load regulation. The perturb and observe based maximum power point tracking algorithm is used for extracting maximum power from solar photovoltaic panels while the battery charging controller is designed using a PI controller. A high-level control algorithm is then designed to switch between the lower level controllers based on different operating conditions such as high state of charge, low state of charge, maximum battery current, and heavy load by respecting the constraints formulated. The developed algorithm is evaluated using theoretical simulation and experimental studies. The simulation and experimental results are presented to validate the proposed technique.

关键词： battery management system     hybrid electric vehicles (HEVs)     maximum power point tracking (MPPT)     solar photovoltaic    

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Fatigue shear performance of concrete beams reinforced with hybrid (glass-fiber-reinforced polymer+ steel

《结构与土木工程前沿（英文）》 2021年 第15卷 第3期   页码 576-594 doi: 10.1007/s11709-021-0728-6

摘要： Reinforced concrete beams consisting of both steel and glass-fiber-reinforced polymer rebars exhibit excellent strength, serviceability, and durability. However, the fatigue shear performance of such beams is unclear. Therefore, beams with hybrid longitudinal bars and hybrid stirrups were designed, and fatigue shear tests were performed. For specimens that failed by fatigue shear, all the glass-fiber-reinforced polymer stirrups and some steel stirrups fractured at the critical diagonal crack. For the specimen that failed by the static test after 8 million fatigue cycles, the static capacity after fatigue did not significantly decrease compared with the calculated value. The initial fatigue level has a greater influence on the crack development and fatigue life than the fatigue level in the later phase. The fatigue strength of the glass-fiber-reinforced polymer stirrups in the specimens was considerably lower than that of the axial tension tests on the glass-fiber-reinforced polymer bar in air and beam-hinge tests on the glass-fiber-reinforced polymer bar, and the failure modes were different. Glass-fiber-reinforced polymer stirrups were subjected to fatigue tension and shear, and failed owing to shear.

关键词： fatigue     shear     hybrid stirrups     hybrid reinforcement     fiber-reinforced polymer    

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Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1440-1449 doi: 10.1007/s11705-023-2333-9

摘要： The composite electrode of CoNiSx and Ti3C2Tx MXene was successfully prepared using a one-step hydrothermal method under the in-situ doping of the cobalt element. The effects of in-situ doping of the cobalt element on the micromorphology and electrochemical performance of the electrodes were investigated. After in-situ doping of the cobalt element, NiS with a needle-like structure was converted into a CoNiSx with petal-like structure. The petal-like CoNiSx with a rough surface was very dense and evenly wrapped on the surface and interlamination of Ti3C2Tx, which helped increase the specific surface area and pore volume of the electrode. Under the identical test conditions, CoNiSx@Ti3C2Tx had a higher specific capacitance and capacitance retention than NiS@Ti3C2Tx. This result indicated that the in-situ doping of the cobalt element promoted the electrochemical performance of the electrode. The energy density of the CoNiSx@Ti3C2Tx/nickel foam (NF)//activated carbon (AC)/NF asymmetric supercapacitor device was 59.20 Wh·kg–1 at a power density of 826.73 W·kg–1, which was much higher than that of NiS@Ti3C2Tx/NF//AC/NF. Three CoNiSx@Ti3C2Tx/NF//AC/NF in series were able to illuminate the light emitting diode lamp for about 10 min, which was higher than the 5 min of three NiS@Ti3C2Tx/NF//AC/NF in series under the same condition. The CoNiSx@Ti3C2Tx/NF//AC/NF with high energy density had better application potential in energy storage than the NiS@Ti3C2Tx/NF//AC/NF.

关键词： MXene     supercapacitor     cobalt doping     structure characterization     electrochemical performance    

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A pseudocapacitive molecule-induced strategy to construct flexible high-performance asymmetric supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1208-1220 doi: 10.1007/s11705-023-2304-1

摘要： The combination of high-voltage windows and bending stability remains a challenge for supercapacitors. Here, we present an “advantage-complementary strategy” using sodium lignosulfonate as a pseudocapacitive molecule to regulate the spatial stacking pattern of graphene oxide and the interfacial architectures of graphene oxide and polyaniline. Flexible and sustainable sodium lignosulfonate-based electrodes are successfully developed, showing perfect bending stability and high electronic conductivity and specific capacitance (521 F·g−1 at 0.5 A·g–1). Due to the resulting rational interfacial structure and stable ion-electron transport, the asymmetric supercapacitors provide a wide voltage window reaching 1.7 V, outstanding bending stability and high energy-power density of 83.87 Wh·kg–1 at 3.4 kW·kg–1. These properties are superior to other reported cases of asymmetric energy enrichment. The synergistic strategy of sodium lignosulfonate on graphene oxide and polyaniline is undoubtedly beneficial to advance the process for the construction of green flexible supercapacitors with remarkably wide voltage windows and excellent bending stability.

关键词： molecular synergy     pseudocapacitive lignosulfonate     flexible electronic devices     asymmetric supercapacitor     wide voltage windows    

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Breeding strategies for increasing yield potential in super hybrid rice

Shihua CHENG,Xiaodeng ZHAN,Liyong CAO

《农业科学与工程前沿（英文）》 2015年 第2卷 第4期   页码 277-282 doi: 10.15302/J-FASE-2015081

摘要： Super hybrid rice breeding is a new breeding method combining semi-dwarf breeding and heterosis breeding using germplasm and gene-environment interactions. This paper reviews the breeding strategies of super hybrid rice breeding in China, focusing on the utilization of heterosis of indica and japonica subspecies, construction of ideal plant architecture and pyramiding of disease resistant genes in restorer lines. To develop super hybrid rice, considerable effort should be made to explore genes related with high yield, good quality, resistance to pests and diseases, tolerance to stresses. Molecular breeding methods in combination with crossing techniques should be adopted in super hybrid rice breeding.

关键词： super hybrid rice     breeding strategies     yield potential    

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标题 作者 时间 类型 操作

Phosphorus-doped Ni–Co sulfides connected by carbon nanotubes for flexible hybrid supercapacitor

期刊论文

CC@BCN@PANI core-shell nanoarrays as ultra-high cycle stability cathode for Zn-ion hybrid supercapacitors

期刊论文

the grain boundary: a promising strategy to configure NiCoPO/NiCoP nanowire arrays for ultra-stable supercapacitor

期刊论文

Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor

期刊论文

Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications

期刊论文

Intelligent hybrid power generation system using new hybrid fuzzy-neural for photovoltaic system and

Alireza REZVANI,Ali ESMAEILY,Hasan ETAATI,Mohammad MOHAMMADINODOUSHAN

期刊论文

Robust ensemble of metamodels based on the hybrid error measure

期刊论文

Design method and verification of a hybrid prosthetic mechanism with energy-damper clutchable device

期刊论文

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

期刊论文

Diffusion process in enzyme–metal hybrid catalysts

期刊论文

Powertrain control of a solar photovoltaic-battery powered hybrid electric vehicle

P. PADMAGIRISAN, V. SANKARANARAYANAN

期刊论文

Fatigue shear performance of concrete beams reinforced with hybrid (glass-fiber-reinforced polymer+ steel

期刊论文

Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

期刊论文

A pseudocapacitive molecule-induced strategy to construct flexible high-performance asymmetric supercapacitors

期刊论文

Breeding strategies for increasing yield potential in super hybrid rice

Shihua CHENG,Xiaodeng ZHAN,Liyong CAO

期刊论文